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  <front>
    <journal-meta>
      <journal-id journal-id-type="publisher-id">journal</journal-id>

      <journal-title-group>
        <journal-title>Вестник Объединенного института высоких температур</journal-title>
        <abbrev-journal-title abbrev-type="publisher">Вестник ОИВТ РАН</abbrev-journal-title>
      </journal-title-group>

      <issn pub-type="epub">2658-669X</issn>

      <publisher>
        <publisher-name>ОИВТ РАН</publisher-name>
      </publisher>
    </journal-meta>

    <article-meta>
      <article-id pub-id-type="publisher-id">64</article-id>
      <article-id pub-id-type="doi"></article-id>

      <title-group>
        <article-title>О неэффективности галогенсодержащих соединений как подавителей воспламенения метано-кислородных смесей за ударными волнами</article-title>
        <trans-title-group xml:lang="en">
          <trans-title>
            On inefficiency of suppression of methane-oxygen mixtures autoignition by halogenated hydrocarbons
          </trans-title>
        </trans-title-group>
      </title-group>

      <contrib-group>
        <contrib contrib-type="author">
          <name-alternatives>
            <name xml:lang="ru">
              <surname></surname>
              <given-names> </given-names>
            </name>
            <name xml:lang="en">
              <surname>Drakon</surname>
              <given-names>A.V.</given-names>
            </name>
          </name-alternatives>
          <xref ref-type="aff" rid="id1">ОИВТ РАН</xref>
        </contrib>

        <contrib contrib-type="author">
          <name-alternatives>
            <name xml:lang="ru">
              <surname></surname>
              <given-names> </given-names>
            </name>
            <name xml:lang="en">
              <surname>Eremin</surname>
              <given-names>A.V.</given-names>
            </name>
          </name-alternatives>
          <xref ref-type="aff" rid="id2">ОИВТ РАН</xref>
        </contrib>

      </contrib-group>

      <aff-alternatives id="id1">
        <aff xml:lang="ru">
          <label>ОИВТ РАН</label>
          <institution>Объединенный институт высоких температур РАН (Москва, Россия)</institution>
          <addr-line>Москва, Россия</addr-line>
        </aff>
        <aff xml:lang="en">
          <label>JIHT RAS</label>
          <institution>Joint Institute for High Temperatures of the Russian Academy of Sciences (Moscow, Russia)</institution>
          <addr-line>Moscow, Russia</addr-line>
        </aff>
      </aff-alternatives>

      <aff-alternatives id="id2">
        <aff xml:lang="ru">
          <label>ОИВТ РАН</label>
          <institution>Объединенный институт высоких температур РАН (Москва, Россия)</institution>
          <addr-line>Москва, Россия</addr-line>
        </aff>
        <aff xml:lang="en">
          <label>JIHT RAS</label>
          <institution>Joint Institute for High Temperatures of the Russian Academy of Sciences (Moscow, Russia)</institution>
          <addr-line>Moscow, Russia</addr-line>
        </aff>
      </aff-alternatives>

      <pub-date publication-format="electronic" date-type="pub" pub-type="epub" iso-8601-date="2019-08-20">
        <day>20</day>
        <month>08</month>
        <year>2019</year>
      </pub-date>

      <volume>2</volume>
      <issue>12</issue>
      <fpage>56</fpage>
      <lpage>62</lpage>

      <abstract xml:lang="ru">
        <p>В работе экспериментально исследовано влияние добавок йодсодержащих углеводородов CF$_{3}$I и C$_{3}$F$_{7}$I, известных как ингибиторы горения, на воспламенение метано-кислородных смесей за ударными волнами. Полученные температурные зависимости времени индукции показали, что оба ингибитора не только не продемонстрировали заметной ингибирующей активности, но и, напротив, привели к существенному ускорению развития воспламенения, подобно изученным ранее хладонам CCl$_{4}$, CF$_{3}$H и C$_{2}$F$_{4}$Br$_{2}$. Проведенный кинетический анализ позволяет заключить, что существование эффективного галогенсодержащего ингибитора воспламенения метана за ударной волной маловероятно.</p>
      </abstract>

      <abstract xml:lang="en" abstract-type="summary">
        <p>In this work an influence of the additives of iodinated hydrocarbons CF$_{3}$I and C$_{3}$F$_{7}$I (considered as fire suppressants) on shock-induced ignition of methane was experimentally investigated. Observed temperature dependencies of induction times indicate that both suppressors do not show noticeable inhibiting activity at given conditions, but contrary reduce the ignition delay time similarly to previously studied CCl$_{4}$, CF$_{3}$H and C$_{2}$F$_{4}$Br$_{2}$. Performed kinetics analysis allowed to conclude that effective chemical inhibition of methane autoignition by halogenated hydrocarbons is unlikely.</p>
      </abstract>

      <kwd-group kwd-group-type="author-keywords" xml:lang="ru">
        <kwd>метан</kwd>
        <kwd>ударные волны</kwd>
        <kwd>воспламенение</kwd>
        <kwd>ингбирование</kwd>
        <kwd>галогеноалканы</kwd>
      </kwd-group>

      <kwd-group kwd-group-type="author-keywords" xml:lang="en">
        <kwd>methane</kwd>
        <kwd>shock waves</kwd>
        <kwd>ignition</kwd>
        <kwd>inhibition</kwd>
        <kwd>haloalkanes</kwd>
      </kwd-group>

    </article-meta>
  </front>
  <back>
    <ref-list>
      <ref id="ref1">
        <mixed-citation publication-type="other" xml:lang="ru">
          Hastie J. W. // J. Res. Natl. Bur. Stand. — 1973. — Vol. 77A. — P. 733–54         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Hastie J. W. // J. Res. Natl. Bur. Stand. — 1973. — Vol. 77A. — P. 733–54         
        </mixed-citation>
      </ref>
      <ref id="ref2">
        <mixed-citation publication-type="other" xml:lang="ru">
          Westbrook C. K. // Symp. (Int.) Combust. — 1982. — Vol. 19. — P. 127–41         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Westbrook C. K. // Symp. (Int.) Combust. — 1982. — Vol. 19. — P. 127–41         
        </mixed-citation>
      </ref>
      <ref id="ref3">
        <mixed-citation publication-type="other" xml:lang="ru">
          Babushok V., Noto T., Burgess D. R., Hamins A., Tsang W. // Comb. Flame. — 1996. — Vol. 107. — P. 351-67         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Babushok V., Noto T., Burgess D. R., Hamins A., Tsang W. // Comb. Flame. — 1996. — Vol. 107. — P. 351-67         
        </mixed-citation>
      </ref>
      <ref id="ref4">
        <mixed-citation publication-type="other" xml:lang="ru">
          Drakon A., Eremin A. // Comb. Sci. Techn. — 2018. — Vol. 190. — P. 550–55         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Drakon A., Eremin A. // Comb. Sci. Techn. — 2018. — Vol. 190. — P. 550–55         
        </mixed-citation>
      </ref>
      <ref id="ref5">
        <mixed-citation publication-type="other" xml:lang="ru">
          Azatyan V. V., Shebeko Y. N., Yu S. A., Yu N. V. // Rus. J. Phys. Chem B. — 2010. — Vol. 4. — P. 760–768         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Azatyan V. V., Shebeko Y. N., Yu S. A., Yu N. V. // Rus. J. Phys. Chem B. — 2010. — Vol. 4. — P. 760–768         
        </mixed-citation>
      </ref>
      <ref id="ref6">
        <mixed-citation publication-type="other" xml:lang="ru">
          Drakon A. V., Eremin A. V., Korobeinichev O. P., Shvartsberg V. M., Shmakov A. G. // Combust. Explos. Shock Waves. — 2016. — Vol. 52. — P. 375-85         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Drakon A. V., Eremin A. V., Korobeinichev O. P., Shvartsberg V. M., Shmakov A. G. // Combust. Explos. Shock Waves. — 2016. — Vol. 52. — P. 375-85         
        </mixed-citation>
      </ref>
      <ref id="ref7">
        <mixed-citation publication-type="other" xml:lang="ru">
          Drakon A., Eremin A., Matveeva N., Mikheyeva E. // Comb. Flame. — 2017. — Vol. 176. — P. 592–8         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Drakon A., Eremin A., Matveeva N., Mikheyeva E. // Comb. Flame. — 2017. — Vol. 176. — P. 592–8         
        </mixed-citation>
      </ref>
      <ref id="ref8">
        <mixed-citation publication-type="other" xml:lang="ru">
          Drakon A., Eremin A., Emelianov A. // Shock Waves. — 2014. — Vol. 24. — P. 231–7         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Drakon A., Eremin A., Emelianov A. // Shock Waves. — 2014. — Vol. 24. — P. 231–7         
        </mixed-citation>
      </ref>
      <ref id="ref9">
        <mixed-citation publication-type="other" xml:lang="ru">
          Babushok V. I., Linteris G. T., Meier O. C. // Comb. Flame. — 2012. — Vol. 149. — P. 3569–75         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Babushok V. I., Linteris G. T., Meier O. C. // Comb. Flame. — 2012. — Vol. 149. — P. 3569–75         
        </mixed-citation>
      </ref>
      <ref id="ref10">
        <mixed-citation publication-type="other" xml:lang="ru">
          Gaydon A. G., Hurle I. R. The Shock Tube in High Temperature Chemical Physics. — : London: Verlag Chapman and Hall Ltd., 1963         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Gaydon A. G., Hurle I. R. The Shock Tube in High Temperature Chemical Physics. — : London: Verlag Chapman and Hall Ltd., 1963         
        </mixed-citation>
      </ref>
      <ref id="ref11">
        <mixed-citation publication-type="other" xml:lang="ru">
          Kee R. J., Rupley F. M., Miller J. A. CHEMKIN-II: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical kinetics. Report SAND89-8009B. — 1993         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Kee R. J., Rupley F. M., Miller J. A. CHEMKIN-II: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical kinetics. Report SAND89-8009B. — 1993         
        </mixed-citation>
      </ref>
      <ref id="ref12">
        <mixed-citation publication-type="other" xml:lang="ru">
          Frenklach M., Hanson R. K., others $GRI-Mech 3.0$. — 1999         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Frenklach M., Hanson R. K., others $GRI-Mech 3.0$. — 1999         
        </mixed-citation>
      </ref>
      <ref id="ref13">
        <mixed-citation publication-type="other" xml:lang="ru">
          Азатян В. В. Цепные реакции в процессах горения, взрыва и детонации газов. — : ИПХФ РАН, 2017         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Azatyan V. V. Tsepnye reaktsii v protsessakh goreniya, vzryva i detonatsii gazov. — : IPKhF RAN, 2017         
        </mixed-citation>
      </ref>
      <ref id="ref14">
        <mixed-citation publication-type="other" xml:lang="ru">
          Cobos C. J., Croce A. E., Luther K., Troe J. // Z. Phys. Chem. — 2011. — Vol. 225. — P. 1019–28         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Cobos C. J., Croce A. E., Luther K., Troe J. // Z. Phys. Chem. — 2011. — Vol. 225. — P. 1019–28         
        </mixed-citation>
      </ref>
      <ref id="ref15">
        <mixed-citation publication-type="other" xml:lang="ru">
          Cobos C. J., Croce A. E., Luther K., Solter L., Tellbach E., Troe J. // J. Phys. Chem. A. — 2013. — Vol. 117. — P. 11420–29         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Cobos C. J., Croce A. E., Luther K., Solter L., Tellbach E., Troe J. // J. Phys. Chem. A. — 2013. — Vol. 117. — P. 11420–29         
        </mixed-citation>
      </ref>
      <ref id="ref16">
        <mixed-citation publication-type="other" xml:lang="ru">
          Hranisavljevic J., Carroll J. J., Su M. C., Michael J. V. // J. Res. Natl. Bur. Stand. — 1998. — Vol. 30. — P. 859–67         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Hranisavljevic J., Carroll J. J., Su M. C., Michael J. V. // J. Res. Natl. Bur. Stand. — 1998. — Vol. 30. — P. 859–67         
        </mixed-citation>
      </ref>
      <ref id="ref17">
        <mixed-citation publication-type="other" xml:lang="ru">
          Kumaran S. S., Su M. C., Lim K. P., Michael J. V., Wagner A. F., Harding L. B. // J. Phys. Chem. — 1996. — Vol. 100. — P. 7541–49         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Kumaran S. S., Su M. C., Lim K. P., Michael J. V., Wagner A. F., Harding L. B. // J. Phys. Chem. — 1996. — Vol. 100. — P. 7541–49         
        </mixed-citation>
      </ref>
      <ref id="ref18">
        <mixed-citation publication-type="other" xml:lang="ru">
          Kumaran S. S., Su M. C., Michael J. V. // Int. J. Chem. Kinet. — 1997. — Vol. 29. — P. 535–43         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Kumaran S. S., Su M. C., Michael J. V. // Int. J. Chem. Kinet. — 1997. — Vol. 29. — P. 535–43         
        </mixed-citation>
      </ref>
      <ref id="ref19">
        <mixed-citation publication-type="other" xml:lang="ru">
          Lim K. P., Michael J. V. // J. Chem. Phys. — 1993. — Vol. 98. — P. 3919–28         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Lim K. P., Michael J. V. // J. Chem. Phys. — 1993. — Vol. 98. — P. 3919–28         
        </mixed-citation>
      </ref>
      <ref id="ref20">
        <mixed-citation publication-type="other" xml:lang="ru">
          Skorobogatov G. A., Dymov B. P., Tedeev R. S. // J. Gen. Chem. USSR. — 1991. — Vol. 61. — P. 178–85         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Skorobogatov G. A., Dymov B. P., Tedeev R. S. // J. Gen. Chem. USSR. — 1991. — Vol. 61. — P. 178–85         
        </mixed-citation>
      </ref>
      <ref id="ref21">
        <mixed-citation publication-type="other" xml:lang="ru">
          Sehon A. H., Szwarc M. // Proc. R. Soc. London A. — 1951. — Vol. 209. — P. 110–31         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Sehon A. H., Szwarc M. // Proc. R. Soc. London A. — 1951. — Vol. 209. — P. 110–31         
        </mixed-citation>
      </ref>
      <ref id="ref22">
        <mixed-citation publication-type="other" xml:lang="ru">
          Su M. C., Kumaran S. S., Lim K. P., Michael J. V., Wagner A. F., Dixon D. A., Kiefer J. H., DiFelice J. // J. Phys. Chem. — 1996. — Vol. 100. — P. 15827–33         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Su M. C., Kumaran S. S., Lim K. P., Michael J. V., Wagner A. F., Dixon D. A., Kiefer J. H., DiFelice J. // J. Phys. Chem. — 1996. — Vol. 100. — P. 15827–33         
        </mixed-citation>
      </ref>
      <ref id="ref23">
        <mixed-citation publication-type="other" xml:lang="ru">
          Tsang W. // J. Phys. Chem. — 1984. — Vol. 88. — P. 2812–17         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Tsang W. // J. Phys. Chem. — 1984. — Vol. 88. — P. 2812–17         
        </mixed-citation>
      </ref>
      <ref id="ref24">
        <mixed-citation publication-type="other" xml:lang="ru">
          Zalesskii V. Y. // Kinet. Catal. — 1988. — Vol. 29. — P. 453–60         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Zalesskii V. Y. // Kinet. Catal. — 1988. — Vol. 29. — P. 453–60         
        </mixed-citation>
      </ref>
      <ref id="ref25">
        <mixed-citation publication-type="other" xml:lang="ru">
          Michelsen H. A., Simpson W. R. // J. Phys. Chem. A. — 2001. — Vol. 105. — P. 1476-88         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Michelsen H. A., Simpson W. R. // J. Phys. Chem. A. — 2001. — Vol. 105. — P. 1476-88         
        </mixed-citation>
      </ref>
      <ref id="ref26">
        <mixed-citation publication-type="other" xml:lang="ru">
          Pardini S. P., Martin D. S. // Int. J. Chem. Kinet. — 2001. — Vol. 15. — P. 1031–43         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Pardini S. P., Martin D. S. // Int. J. Chem. Kinet. — 2001. — Vol. 15. — P. 1031–43         
        </mixed-citation>
      </ref>
      <ref id="ref27">
        <mixed-citation publication-type="other" xml:lang="ru">
          Baulch D. L., Duxbury J., Grant S. J., Montague D. C. // J. Phys. Chem. Ref. Data. — 1981. — Vol. 10. — P. 1–721         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Baulch D. L., Duxbury J., Grant S. J., Montague D. C. // J. Phys. Chem. Ref. Data. — 1981. — Vol. 10. — P. 1–721         
        </mixed-citation>
      </ref>
      <ref id="ref28">
        <mixed-citation publication-type="other" xml:lang="ru">
          Keating E. L., Matula R. A. // T. J. Chem. Phys. — 1977. — Vol. 66. — P. 1237–44         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Keating E. L., Matula R. A. // T. J. Chem. Phys. — 1977. — Vol. 66. — P. 1237–44         
        </mixed-citation>
      </ref>
      <ref id="ref29">
        <mixed-citation publication-type="other" xml:lang="ru">
          Azatyan V., Saikova G. // Rus. J. Phys. Chem. A. — 2013. — Vol. 87. — P. 1615–21         
        </mixed-citation>
        <mixed-citation publication-type="other" xml:lang="en">
          Azatyan V., Saikova G. // Rus. J. Phys. Chem. A. — 2013. — Vol. 87. — P. 1615–21         
        </mixed-citation>
      </ref>
    </ref-list>
  </back>

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